Inventors:
- Midland MI, US
Matthew T. Pretz - Lake Jackson TX, US
Assignee:
Dow Global Technologies LLC - Midland MI
International Classification:
C07C 5/48
B01J 8/18
B01J 8/26
B01J 8/00
Abstract:
According to one or more embodiments disclosed herein, methods for operating dehydrogenation processes during non-normal operating conditions, such as at start-up, shut-down, system recycle, or unit trip, are described. The methods may include contacting a feed stream with a catalyst in a reactor portion of a reactor system to form a reactor effluent stream, separating at least a portion of the reactor effluent stream from the catalyst, passing the catalyst to a catalyst processing portion and processing the catalyst, wherein processing the catalyst comprises contacting the catalyst with oxygen, passing the catalyst from the processing portion to the reactor portion, wherein the catalyst exiting the processing portion comprises at least 0.001 wt. % oxygen, and contacting the catalyst with supplemental hydrogen, the contacting removing at least a portion of the oxygen from the catalyst by a combustion reaction.